It used magnesium as the counter ion and was based on work by Carl Daniel Ekman. Almost a decade later, the first commercial sulfite pulp mill was built, in Sweden. patent on the use of calcium bisulfite, Ca(HSO 3) 2, to pulp wood in 1867. Roth's use of sulfurous acid to treat wood, then by Benjamin Tilghman's U.S. Chemical processes quickly followed, first with J. While some of the earliest examples of paper made from wood pulp include works published by Jacob Christian Schäffer in 1765 and Matthias Koops in 1800, large-scale wood paper production began in the 1840s with unique, simultaneous developments in mechanical pulping made by Friedrich Gottlob Keller in Germany and by Charles Fenerty in Nova Scotia. The use of wood pulp and the invention of automatic paper machines in the late 18th- and early 19th-century contributed to paper's status as an inexpensive commodity in modern times. By the 1800s, production demands on the newly industrialized papermaking and printing industries led to a shift in raw materials, most notably the use of pulpwood and other tree products which today make up more than 95% of global pulp production. Papermaking using pulp made from hemp and linen fibers from tattered clothing, fishing nets and fabric bags spread to Europe in the 13th century, with an ever-increasing use of rags being central to the manufacture and affordability of rag paper, a factor in the development of printing.
In addition to mulberry, pulp was also made from bamboo, hibiscus bark, blue sandalwood, straw, and cotton. By the 6th century, the mulberry tree was domesticated by farmers in China specifically for the purpose of producing pulp to be used in the papermaking process. The earliest paper produced in China consisted of bast fibers from the paper mulberry (kozo) plant along with hemp rag and net scraps. Pulp used in modern and traditional papermaking is distinguished by the maceration process which produces a finer, more regular slurry of cellulose fibers which are pulled out of solution by a screen and dried to form sheets or rolls. Strips of bark or bast material were woven together, beaten into rough sheets, dried, and polished by hand.
Before the widely acknowledged invention of papermaking by Cai Lun in China around 105 AD, paper-like writing materials such as papyrus and amate were produced by ancient civilizations using plant materials which were largely unprocessed.
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